菜单
  
    摘要目前,吸附工艺在放射性废水处理中得到很快发展,该工艺主要利用吸附剂对放射性核素有很高的选择性。吸附材料的吸附性能与其吸附目标核素有很大的关系,一种吸附剂只对一种或几种放射性核素同时有很高的选择性和吸附容量[1]。近年来国内外已将沸石应用于放射性废水处理。沸石在水处理工艺中常用作为吸附剂,但它同时还兼有离子交换剂和过滤剂的作用[2-3]。沸石与其他无机吸附剂相比,具有较大的吸附能力和净化效果,本试验采用人工模拟放射性废水,进行吸附动态实验,得出沸石吸附的影响因素和最佳控制条件,从而确定影响沸石吸附效果的因素,pH 值是影响铀去除率的主要因素, 吸附铀的最佳pH=2-3, 铀初始浓度越高, 沸石的吸附量越高,吸附效率越低。同时考察不同孔结构的沸石等有序多孔材料的吸附效率,得到有序多孔吸附材料的孔径与其吸附性能之间的关联规律,为铀矿冶放射性废水治理及其中放射性核素的分离、富集和资源化利用提供理论8111
    和实验依据。
    关键词 低放射性废水  铀  吸附  沸石  多孔材料 Title   Title   Title   Title  Adsorption Behavior of Uranium-beating Wastewater in
     Ordered Porous Materials                           
     
    Abstract Abstract Abstract Abstract      
    Currently,the adsorption which mainly uses the high selectivity of the
    adsorbent for radionuclides  has been quickly developed in the radioactive
    wastewater treatment.The adsorption  properties of the adsorption material
    has a great relationship with the target nuclide of the adsorption-an
    adsorbent has a high selectivity and adsorption capacity for only one or
    a few radionuclides.Zeolite has been used in the radioactive wastewater
    treatment at home and abroad in recent years,and  is often used as adsorbent
    in water treatment process,but it also acts as the ion exchange agent and
    the filtering agent at the same time.Compared with other inorganic
    adsorbent,zeolite has a larger capacity of adsorption and effect of
    purifying.This test conducted adsorption dynamic experiments using the
    artificial simulation of radioactive wastewater,and obtained the factors
    affecting the adsorption of zeolite and optimal controlling
    conditions,thus determining the factors affecting the effect of zeolite  
    adsorption.pH is a major factor affecting uranium removal efficiency,and
    the optimum of which for the adsorption of uranium is pH=2-3.The higher
    uranium initial concentration,the higher adsorption capacity of the
    zeolite,and the lower adsorption efficiency.Meanwhile,the adsorption
    efficiency of ordered porous materials like the different pore structure
    of zeolites was investigated,getting the association rules between the
    aperture and its adsorption properties of the ordered porous adsorbent
    material, and providing the theoretical and experimental basis for the
    radioactive wastewater treatment of uranium mining  and milling and for the
    separation, enrichment and resource utilization of radionuclides.  
    Keywords   low-level  radioactive  wastewater   uranium   adsorption    
    zeolites   porous  materials 目   次
     
    1 绪论 .. 1
    1.1 研究背景及目标 .. 1
    1.2 放射性废水介绍及其处理现状 .. 2
    1.2.1 放射性废水的来源和特征. 2
    1.2.2 放射性废水的危害 . 3
    1.2.3 通过吸附处理放射性废水的现状. 3
    1.3 放射性废水中铀的测量方法 . 3
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