The results showed that when the ratio of monomer to monomer was between 1: 1 and 1: 1.5, 3%, the reaction temperature is 82 ℃, the reaction time is 5h, the synthetic resin film, calcium ion stability, corrosion resistance is better.

And then KH550, KH560 for silicone modification, and synthetic resin on the film test. Experiments show that: modified with silicone, is conducive to acrylic resin film water resistance, heat resistance. When the amount of initiator is 3%, the reaction temperature is 82 ℃, the stirring speed is 150r / min-200r / min, the amount of organic silicon is 6%, the reaction time is 5 hours. The synthetic silicone modified acrylic resin has

better film Nature, corrosion resistance, hydrophobicity, greatly improving the shortcomings of water-based acrylic resin.

In the emulsion polymerization method, OP-10 was introduced, and the optimum dosage and ratio of the emulsion polymerization system were determined by analyzing the particle size of the acrylic acid synthesized by emulsion polymerization, the separation of calcium   ions   and   the   analysis   of   the   film.   :   The   pre-emulsion-seed     emulsion polymerization process, the reaction temperature is 80 ℃, the amount of emulsifier is  3%,the amount of NaHCO3 is 0.3%, the ratio of OP-10 to SDBS is 2: 1, the particle size distribution is uniform, The best performance, the best film performance.

Keywords:water-borne acrylic；silicone modified；solution polymerization；emulsion polymerization

目录

第一章绪论 1

1.1 前言 1

1.2 丙烯酸树脂发展历程 1

1.3 丙烯酸树脂的分类 2

1.3.1 热塑性丙烯酸树脂： 2

1.3.2 热固性丙烯酸树脂： 2

1.4 水性丙烯酸树脂研究现状及存在的问题 2

1.5 水性丙烯酸树脂的聚合方法 3

1.5.1 自由基溶液聚合 3

1.5.2 自由基乳液聚合 4

1.5.3 悬浮聚合 4

1.5.4 本体聚合 5

1.6 水性丙烯酸树脂的成膜机理 5

1.6.1 水稀释性丙烯酸树脂的成膜机理 5

1.6.2 水乳型丙烯酸树脂的成膜机理 6

1.7 水性丙烯酸树脂的应用 6

1.7.1 在水性涂料领域中的应用： 6

1.7.2 在水性胶黏剂方面的应用： 7

1.7.3 在水性油墨、上光油方面的应用： 7

1.7.4 在其他方面的应用： 7

1.8 水性丙烯酸树脂的改性 7

1.8.1 物理共混改性 7

1.8.2 化学改性 8

1.9 本课题研究的内容、目的和意义 10

第二章实验 12

2.1 实验原料