摘要本课题研究的是电镀法制备新型三维网状结构FeCoNi三元合金制氢催化剂及探索催化剂在制氢实验过程中的性能。为了找出最优制备条件，研究不同电镀液温度、电流密度波形、电镀时间、电镀液浓度等对催化剂制备的影响，对制氢效率的影响。通过实验发现：当电镀液CoCl2浓度为40g/L,FeSO4浓度为30g/L，NiCl2浓度为20g/L，硼酸浓度为30g/L，电镀环境为20分钟的电镀时间、40摄氏度的电镀液温度、1.0A/cm2的直流电流密度时，制氢效果最好。69102

该论文有图19幅，表4个，参考文献9篇。

毕业论文关键词：电镀  制氢  三维网状  三元合金 

Preparation and properties of a novel three dimensional network structure FeCoNi three element alloy for hydrogen production

Abstract

The experimental study was made on the preparation of a new three-dimensional network structure of FeCoNi three alloy catalyst for hydrogen production and the performance of the catalyst in the process of hydrogen production. In order to find out the optimal electroplating conditions, the effects of different plating solution temperature, current density, plating time and plating solution concentration on the catalyst preparation were studied. Through the experiment find that when the electroplating solution concentration of CoCl2 is 40g / L, FeSO4 concentration is 30g / L, the concentration of NiCl2 is 20g / L, the concentration of H3BO3 is 30g / L, electroplating environment for 20 minutes of electroplating time, 40℃ temperature of the electroplating solution, 1.0A /cm2 current density, the hydrogen result is the best.

Keywords: Electroplate  Hydrogen production 3D mesh  Three element alloy

目  录

摘要 I

Abstract II

图清单 V

表清单 V

1绪论 1

1.1氢能 1

1.2制氢技术发展 1

1.3金属催化剂 2

1.4电镀 2

2实验 4

2.1 实验材料 4

2.2 实验仪器 4

2.3 实验 4

3.催化剂制氢性能实验研究 8

3.1制氢测试方法 8

3.2制氢实验具体步骤 9

3.3电镀条件不同对催化剂制氢的影响 9

4.表征 19

4.1 SEM 19

4.2 EDX 19

5结论 23

5.1实验结论 23

5.2关于未来氢能源的想法 24

参考文献 25

致谢 26

图清单

图序号 图名称 页码

图2-1 电镀装置示意图 6

图2-2 电镀前 7

图2-3 电镀后 7

图3-1 催化制氢实验装置示意图